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Abstract Metal-free electrocatalysts represent a main branch of active materials for oxygen evolution reaction (OER), but they excessively rely on functionalized conjugated carbon materials, which substantially restricts the screening of potential efficient carbonaceous electrocatalysts. Herein, we demonstrate that a mesostructured polyacrylate hydrogel can afford an unexpected and exceptional OER activity – on par with that of benchmark IrO 2 catalyst in alkaline electrolyte, together with a high durability and good adaptability in various pH environments. Combined theoretical and electrokinetic studies reveal that the positively charged carbon atoms within the carboxylate units are intrinsically active toward OER, and spectroscopic operando characterizations also identify the fingerprint superoxide intermediate generated on the polymeric hydrogel backbone. This work expands the scope of metal-free materials for OER by providing a new class of polymeric hydrogel electrocatalysts with huge extension potentials. 

ArcticDEM provides the public with an unprecedented opportunity to access very high-spatial resolution digital elevation models (DEMs) covering the pan-Arctic surfaces. As it is generated from stereo-pairs of optical satellite imagery, ArcticDEM represents a mixture of a digital surface model (DSM) over a non-ground areas and digital terrain model (DTM) at bare grounds. Reconstructing DTM from ArcticDEM is thus needed in studies requiring bare ground elevation, such as modeling hydrological processes, tracking surface change dynamics, and estimating vegetation canopy height and associated forest attributes. Here we proposed an automated approach for estimating DTM from ArcticDEM in two steps: (1) identifying ground pixels from WorldView-2 imagery using a Gaussian mixture model (GMM) with local refinement by morphological operation, and (2) generating a continuous DTM surface using ArcticDEMs at ground locations and spatial interpolation methods (ordinary kriging (OK) and natural neighbor (NN)). We evaluated our method at three forested study sites characterized by different canopy cover and topographic conditions in Livengood, Alaska, where airborne lidar data is available for validation. Our results demonstrate that (1) the proposed ground identification method can effectively identify ground pixels with much lower root mean square errors (RMSEs) (<0.35 m) to the reference data than the comparative state-of-the-art approaches; (2) NN performs more robustly in DTM interpolation than OK; (3) the DTMs generated from NN interpolation with GMM-based ground masks decrease the RMSEs of ArcticDEM to 0.648 m, 1.677 m, and 0.521 m for Site-1, Site-2, and Site-3, respectively. This study provides a viable means of deriving high-resolution DTM from ArcticDEM that will be of great value to studies focusing on the Arctic ecosystems, forest change dynamics, and earth surface processes. 

Boreal forest heights are associated with global carbon stocks and energy budgets. The launch of the Advanced Topographic Laser Altimeter System (ATLAS) onboard the NASA's Ice, Cloud and Land Elevation Satellite (ICESat‐2) enables canopy vertical structure measurement at a global scale. However, with a photon‐counting laser system, ICESat‐2 contains high uncertainties in the estimated canopy heights, requiring appropriate quality control before being applied to canopy height modelling.

We adopted a multivariate quality control approach (i.e. the Cook's distance) to improve the quality of ICESat‐2 samples. The controlled ICESat‐2 data were then input as the response variable for predicting boreal forest heights based on spatially continuous satellite data and machine learning (ML) regression models. The examined ML regressors include artificial neural networks (ANN), gradient boosting machine (GBM), random forest (RF) and support vector regression (SVR).

The proposed quality control effectively removes low‐quality ICESat‐2 samples and enhances the correlations between ICESat‐2 and airborne laser scanning (ALS) observations. Moreover, the controlled ICESat‐2 samples help achieve a trade‐off between sample quality and quantity for all ML regressors, generating close canopy heights to ALS‐derived counterparts. Overall, RF and GBM make better canopy height predictions than ANN and SVR. Of all explanatory variables, the normalized difference vegetation index calculated based on the first red edge band of Sentinel‐2 (NDVIredEdge1) is considered the most important.

The proposed quality control on ICESat‐2 sample selection and canopy height model (CHM) development workflow will greatly benefit forest structure investigations in the Arctic community.

 

Previous studies discovered a spatially heterogeneous expansion of Siberian larch into the tundra of the Polar Urals (Russia). This study reveals that the spatial pattern of encroachment of tree stands is related to environmental factors including topography and snow cover. Structural and allometric characteristics of trees, along with terrain elevation and snow depth were collected along a transect 860 m long and 80 m wide. Terrain curvature indices, as representative properties, were derived across a range of scales in order to characterize microtopography. A density-based clustering method was used here to analyze the spatial and temporal patterns of tree stems distribution. Results of the topographic analysis suggest that trees tend to cluster in areas with convex surfaces. The clustering analysis also indicates that the patterns of tree locations are linked to snow distribution. Records from the earliest campaign in 1960 show that trees lived mainly at the middle and bottom of the transect across the areas of high snow depth. As trees expanded uphill following a warming climate trend in recent decades, the high snow depth areas also shifted upward creating favorable conditions for recent tree growth at locations that were previously covered with heavy snow. The identified landscape signatures of increasing tall vegetation, and the effects of microtopography and snow may facilitate the understanding of treeline dynamics at larger scales.